Ok, currently my AD sites and services has the default site named "Default-First-Site-Name" with all 3 domain controllers/global catalog servers. At my main facility I have an IP scheme of 192.168.1.xxx/24 and at my colo facility I have an IP scheme of 192.168.2.xxx/24. What you are saying is create a new site name colo, for example and create a new subnet of 192.168.2.0/24 select the site that associates with 192.168.2.0 and then move the colo DC server in default to the new colo site I created? If that's true, then active directory will first look at the "Default-First-Site-Name", if both those 2 domain controllers are down then pcs and servers will look to the second site?
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Prioritize Domain Controllers in AD